纳米铝热剂薄膜因具有高能量、快速点火燃烧等特性,在微点火器件等领域有一定的应用。介绍了电泳沉积制备铝热剂薄膜的原理及技术优点,总结了多种类型铝热剂薄膜的制备工艺,简介了电泳沉积技术制备三维多孔铝热剂薄膜的进展,提出了优化纳米铝热剂薄膜的方向以及在微点火器上的应用。
Nano-thermite is applied in micro-igniter due to its high heat release,rapid ignition and superior combustion properties.The principle and advantages of electrophoretic deposition nanothermite were introduced.The preparation process parameters of thermite films were summarized.And the research progress of 3D porous thermite films prepared by electrophoretic deposition was summarized.The direction of optimizing nano-thermite film and its application in micro-igniter were introduced.
[1] Kasztankiewicz A,Gańczyk-Specjalska K,Zygmunt A,et al.Application and properties of aluminum in rocket propellants and pyrotechnics[J].Journal of Elementology,2018,23(1):321-331.
[2] Elbasuney S,Zaky M G,Radwan M,et al.Stabilizedsuper-thermite colloids:a new generation of advanced highly energetic materials[J].Applied Surface Science,2017,419:328-336.
[3] Zhou X,Torabi M,Lu J,et al.Nanostructured energetic composites:synthesis,ignition/combustion modeling,and applications[J].ACS Applied Materials & Interfaces,2014,6(5):3058-3074.
[4] 周超,李国平,罗运军.纳米铝热剂的研究进展[J].化工新型材料,2010,38(S1):4-7.
[5] 贾栓柱,杜仕国,闫军.纳米铝热剂的制备与应用研究现状[J].化工新型材料,2018,46(8):261-264.
[6] He W,Liu P J,He G Q,et al.Highly Reactive metastable intermixed composites (MICs):preparation and characterization[J].Advanced Materials,2018,30:e1706293.
[7] Rossi C,Zhang K,Esteved D,et al.Nanoenergetic materials for MEMS:a review[J].Journal of Microelectromechanical Systems,2007,16(4):919-931.
[8] Deng J,Li G,Shen L,et al.Application of Al/B/Fe2O3 nano thermite in composite solid propellant[J].Bulletin of Chemical Reaction Engineering & Catalysis,2016,11(1):109-114.
[9] 张博斌,杨亦婷.基于微机电系统的固体微推进系统研究进展[J].中国航天,2018(8):63-67.
[10] Sullivan K T,Worsley M A,Kuntz J D.Electrophoretic deposition of binary energetic composites[J].Combustion & Flame,2012,159(6):2210-2218.
[11] Sullivan K T,Kuntz J D,Gash A E.Electrophoretic deposition and mechanistic studies of nano-Al/CuO thermites[J].Journal of Applied Physics,2012,112(2):141.
[12] Besra L,Liu M.A review on fundamentals and applications of electrophoretic deposition (EPD)[J].Progress in Materials Science,2007,52(1):1-61.
[13] Corni I,Ryan M P,Boccaccini A R.Electrophoretic deposition:from traditional ceramics to nanotechnology[J].Journal of the European Ceramic Society,2008,28(7):1353-1367.
[14] Sarkar P,Nicholson P S.Mechanism and kinetics of electrophoretic deposition of Al2O3[J].Journal of the American Ceramic Society,1995,78:3165.
[15] Derjaguin B,Landau L.Theory of the stability of strongly charged lyophobic sols and of the adhesion of strongly charged-particles in solutions of electrolytes[J].Progress in Surface Science,1993,43(1-4):30.
[16] Sarkar P,Nicholson P S.Electrophoretic deposition (EPD):mechanisms,kinetics,and application to ceramics[J].Journal of the American Ceramic Society,1996,79(8):1987.
[17] Zhang D X,Li X M,Qin B,et al.Electrophoretic deposition and characterization of nano-Al/Fe2O3 thermites[J].Materials Letters,2014,120(4):224-227.
[18] Zhang D X,Li X M.Fabrication and kinetics study of Nano-Al/NiO thermite film by electrophoretic deposition[J].Journal of Physical Chemistry A,2015,119(20):4688-4694.
[19] Zhu Y H,Li X M,Zhang D X,et al.Tuning the surface charges of MoO3 by adsorption of polyethylenimine to realize the electrophoretic deposition of high-exothermic Al/MoO3 nanoenergetic films[J].Materials and Design,2016,109:652-658.
[20] Sui H T,Atashin S,Wen J Z.Thermo-chemical and energetic properties of layered nano-thermite composites[J].Thermochimica Acta,2016,642:17-24.
[21] 郭茜,黎学明,郭晓刚.水溶液中电泳沉积制备纳米铝热剂Al/Fe2O3[J].化工新型材料,2016,44(11):210-212.
[22] 马小霞,胡艳,张伟,等.电泳沉积法制备纳米Al/Bi2O3铝热剂薄膜的研究[J].爆破器材,2017,46(3):1-5.
[23] Guo X G,Li X M,Chuan L,et al.Facile approach to the green synthesis of novel ternary composites with excellent superhydrophobic and thermal stability property:an expanding horizon[J].Chemical Engineering Journal,2017,309:240-248.
[24] Guo X G,Chuan L,Jiang X,et al.Remarkably facile fabrication of extremely superhydrophobic high-energy binary composite with ultralong lifespan[J].Chemical Engineering Journal,2018,335:843-854.
[25] Zhang D X,Xiang Q,Li X M.Highly reactive Al-Cr2O3 coating for electric-explosion applications[J].RSC Advances,2016,6(103):100790-100795.
[26] Zhang D X,Xiang Q.Electrophoretic fabrication of an Al-Co3O4 reactive nanocomposite coating and its application in a microignitor[J].Industrial & Engineering Chemistry Research,2016,55(30):8243-8248.
[27] Yin Y J,Li X M.Building energetic material from novel salix leaf-like CuO and nano-Al through electrophoretic deposition[J].Bulletin of the Korean Chemical Society,2016,37(11):1827-1830.
[28] Yin Y J,Li X M,Shu Y J,et al.Highly-reactive Al/CuO nanoenergetic materials with a tubular structure[J].Materials and Design,2017,117:104-110.
[29] Yin Y J,Li X M.Al/CuO composite coatings with nanorods structure assembled byelectrophoretic deposition for enhancing energy released[J].Vacuum,2019,163:216-223.
[30] Chiang Y C,Wu M H.Assembly and reaction characterization of a novel thermite consisting aluminum nanoparticles and CuO nanowires[J].Proceedings of the Combustion Institute,2017,36(3):4201-4208.
[31] Hu B,Zhang W C,Yu C P,et al.Electrochemical synthesis of Al/CuO thermite films on copper substrates[J].Industrial & Engineering Chemistry Research,2019,58(17):7131-7138.
[32] Yin Y J,Li X M,Shu Y J,et al.Fabrication of electrophoretically deposited,self-assembled three-dimensional porous Al/CuO nanothermite films for highly enhanced energy output[J].Materials Chemistry and Physics,2017,194:182-187.
[33] Ma X X,Cheng S X,Hu Y,et al.Integrating micro-ignitors with Al/Bi2O3/graphene oxide composite energetic films to realize tunable ignition performance[J].Journal of Applied Physics,2018,123(9):095305.
[34] Sullivan K T,Kuntz J D,Gash A E.Fine patterning of thermites for mechanistic studies and microenergetic applications[J].International Journal of Energetic Materials and Chemical Propulsion,2013,12(6):511-528.
[35] Sullivan K T,Zhu C,Duoss E,et al.Controlling material reactivity using architecture[J].Advanced Materials,2016,28(10):1934-1939.
[36] Sullivan K T,Zhu C,Tanaka D J,et al.Electrophoretic deposition of thermites onto micro-engineered electrodes prepared by Direct-Ink Writing[J].Journal of Physical Chemistry B,2013,117(6):1686-1693.
[37] 李婷婷,李家宽,胡艳,等.纳米Al-CuO/氧化石墨烯含能点火桥膜的制备与电爆性能研究[J].火工品,2018,1:15-19.
基金资助
国家自然科学基金项目(61605188);四川省应用基础研究面上项目(2018JY0479);西华大学青年学者后备人才资助项目(21030027)
PDF
